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ammonium acetate : ウィキペディア英語版
ammonium acetate

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Ammonium acetate is a chemical compound with the formula NH4C2H3O2 (or C2H4O2.NH3 or C2H7NO2 or CH3COONH4). It is a white solid and can be derived from the reaction of ammonia and acetic acid. It is available commercially and, depending on grade, can be rather inexpensive.
== Uses and distinctive properties ==
As the salt of a weak acid and a weak base, ammonium acetate has a number of distinctive properties.
*NH4C2H3O2 is occasionally employed as a biodegradable de-icing agent.
*It is often used with acetic acid to create a buffer solution, one that can be thermally decomposed to non-ionic products
*Ammonium acetate is useful as a catalyst in the Knoevenagel condensation and as a source of ammonia in the Borch reaction in organic synthesis.
*It is a relatively unusual example of a salt that melts at low temperatures.
*Can be used with distilled water to make a protein precipitating reagent.
*Is often used as an aqueous buffer for ESI mass spectrometry of proteins and other molecules.
*Useful in dialysis as part of a protein purification step to remove contaminants via diffusion.
Ammonium acetate is volatile at low pressures. Because of this, it has been used to replace cell buffers with non-volatile salts in preparing samples for mass spectrometry.〔(Berman et al., 2008. ''J Am Soc Mass Spectrom'', 19:1230-1236. )〕 It is also popular as a buffer for mobile phases for HPLC with ELSD detection for this reason. Other volatile salts that have been used for this include ammonium formate.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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